A.Na2CO3为强碱弱酸盐,溶液呈碱性,故A错误;
B.AlCl3为强酸弱碱盐,溶液呈酸性,故B正确;
C.NaCl为强酸强碱盐,在溶液中不水解,溶液显中性,故C错误;
D.CH3COONa为强碱弱酸盐,水溶液呈碱性,故D错误.
故选B.
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