不同的名词,对这两种后置定语的选择是有区别的,有的只能用to do,有的只可用of doing,有的两种都可以，意思是没有区别的，现解释如下:

⑴conclusion, decision, permission, agreement, refusal, determination, proposal, resolution等,一般用不定式作后置定语。

如:

He has drawn a conclusion to go abroad with his family.(不用of winning)

他已作出了携家去国外的决定。

⑵hope, risk, possibility, impossibility, probability, intention, prospect, responsiblility, aim等,一般只能用of doing作后置定语。

如:

He will run the risk of losing his life to save the child.

他将冒生命危险去救那个孩子。

⑶way, chance, need, necessity, right, freedom, power, opportunity,ability等,既可用不定式短语,又可用of doing短语作后置定语。

如:

Their chance to go(of ging) abroad was lost.

他们失去了出国的机会。

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